| ||
|
| ||
|
doi: 10.24412/2687-1092-2023-10-405-414
1VNIIOkeangeologia, St. Petersburg, Russia 2Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russia
|
|
Abstract. Authigenic carbonate mineralization in the gas hydrate-bearing seep “VNIIOkeangeology” located in the Deryugin Basin of the Sea of Okhotsk was studied. A feature of the studied carbonates is the heavy carbon isotope composition (δ13C) in the Mg-calcite sample (up to +9.3‰), as well as the presence of ikaite, an unstable mineral (CaCO3 6H2O), crystallizing at low temperatures. A model for the formation of the discovered authigenic carbonates under conditions of early diagenesis is proposed: destruction of organic matter and methane generation. The processes of anaerobic oxidation of methane were not involved in the crystallization of carbonates. Keywords: ikaite, Mg calcite, Sea of Okhotsk, Deryugin Basin, early diagenesis, gas hydrates
REFERENCES Astakhova N.V. Authigenic formations in Late Cenozoic sediments of the marginal seas of eastern Asia. Vladivostok: Dalnauka, 2007, 244 p. Derkachev A.N., Borman G., Greinert J., Mozherovsky A.V. Authigenic carbonate and barite mineralization in sediments of the Deryugin depression (Sea of Okhotsk) // Lithology and Mineral Resources. 2000. No. 6. P. 568–585. Derkachev A.N., Nikolaeva N.A. Features of authigenic mineralogenesis in sediments of the Sea of Okhotsk. Far Eastern seas of Russia. Book 3. V.A. Akulichev and R.G. Kulinich, ed. M.: Nauka, 2007. pp. 223–239. Derkachev A.N., Obzhirov A.I., Borman G., Greinert J., Suess E. Authigenic mineral formation in areas of cold gas-fluid emanations at the bottom of the Sea of Okhotsk // Conditions for the formation of bottom sediments and associated minerals. Vladivostok: Dalnauka, 2002, p. 47–60. Derkachev A.N., Nikolaeva N.A., Tsoi I.B., Baranov B.V., Barinov N.N., Mozherovsky A.V., Krylov A.A., Kuznetsov A.B., Minami H., Hachikubo A. A Long-Lived Center of Gas–Fluid Emanations on the Western Slope of the Kuril Basin (Sea of Okhotsk) // Lithology and Mineral Resources. 2021. Vol. 56. No. 4. P. 309–332. doi: 10.1134/S0024490221040027 Krylov A.A., Logvina E.A., Matveeva T.V., Prasolov E.M., Sapega V.F., Demidova A.L., Radchenko M.S. Ikaite (CaCO3•6H2O) in bottom sediments of the Laptev Sea and the role of anaerobic oxidation of methane in the process of its formation // Notes of the Russian Mineralogical Society. 2015. No. 4. P. 61-75. Krylov A.A., Khlystov O.M., Semenov P.B., Sagidullin A.K., Malyshev S.A. and others. Sources of Hydrocarbon Gases in the Kedr Mud Volcano, Southern Basin of Lake Baikal: Results of Experimental Studies // Lithology and Mineral Resources. 2023a. Vol. 58. Is. 6. P. 534–543. doi: 10.1134/S0024490223700335 Krylov A.A., Logvina E.A., Zakov E.A., Urvantsev D.M., Semenov P.B., Malyshev S.A., Gusev E.A. Mechanisms of ikaite formation in bottom sediments of the Arctic shelf. In the book: Geology of seas and oceans: Materials of the XXV International Scientific Conference (School) on Marine Geology. T. 1. M., IO RAS. 2023b. pp. 92-95. Lein A.Yu. Authigenic carbonate formation in the ocean // Lithology and Mineral Resources. 2004. No. 1. P. 3-35. Lein A.Yu., Galchenko V.F., Pokrovsky B.G., Shabaeva I.Yu., Chertkova L.V., Miller Yu.M. Marine carbonate nodules as a result of microbial oxidation of methane gas hydrate in the Sea of Okhotsk // Geochemistry. 1989. No. 10. pp. 1396–1406. Logvina E.A. Various scenarios for the formation of authigenic minerals in sediments of fluid discharge sites. // Bulletin of St. Petersburg State University. Ser. 7. 2008. Is. 4. pp. 46-61. Logvina E.A., Krylov A.A., Matveeva T.V., Maksimov F.E., Kuznetsov V.Yu. Autigenesis of carbonates in sediments of the gas-hydrate-bearing structure CHAOS (Sea of Okhotsk) // Bulletin of St. Petersburg State University. Geosciences. 2022. Vol. 67. No. 1. P. 50-73. doi: 10.21638/spbu07.2022.103 Prasolov E.M., Lokhov K.I., Logvina E.A., Mazurenko L.L., Soloviev V.A., Blinova V.N., Ivanov M.K. Origin of carbonates in areas of modern underwater fluid discharge according to isotope geochemistry data (Black and Okhotsk Seas, Gulf of Cadiz) // Regional Geology and Metallogeny. 2006. No. 28. P.158-173. Tishchenko P.Ya., Derkachev A.N., Pavlova G.Yu., Suess E., Wahlmann K., Borman G., Greinert J. Formation of carbonate nodules in places where methane is released on the seabed // Pacific Geology. 2001. Vol. 20. No. 3. P. 58-67. Shakirov R.B., Sorochinskaya A.V., Yatsuk A.V., Aksentov K.I., Karabtsov A.A., Vovna V.I., Osmushko I.S., Korochentsev V.V. Ikaite in the zone of methane anomaly on the continental slope of the Sea of Japan // Vestnik KRAUNC. Geosciences. 2020. No. 2. Issue. 46. pp. 72-84. doi: 10.31431/1816-5524-2020-2-46-72-84 Bischoff J.L., Fitzpatrick J.A., Rosenbauer R.J. The solubility and stabilization of ikaite (CaCO3·6H2O) from 0o to 25oC; environmental and paleoclimatic implications for thinolite tufa // Journal of Geology. 1993. Vol. 101. Is. 1. P. 21–33. doi: 10.1086/648194 Burton Е.A. Controls on marine carbonate cement mineralogy: rеviеw and reassessment // Сhеmiсal Gеology. 1993. Vol. 105. Is. 1-3. P. 163–179. doi: 10.1016/0009-2541(93)90124-2 Chaka A.M. Quantifying the Impact of Magnesium on the Stability and Water Binding Energy of Hydrated Calcium Carbonates by Ab Initio Thermodynamics // J. Phys. Chem. A. 2019. Vol. 123. P. 2908–2923. doi: 10.1021/acs.jpca.9b00180 Greinert J., Bollwerk S.M., Derkachev A. et al. Massive barite deposits and carbonate mineralization in the Derugin Basin, Sea of Okhotsk: precipitation processes at cold seep sites // Earth and Planetary Science Letters. 2002. Vol. 203. Is. 1. P. 165–180. doi: 10.1016/S0012-821X(02)00830-0 Greinert J., Derkachev A. Glendonites and methane-derived Mg-calcites in the Sea of Okhotsk, Eastern Siberia: implications of a venting-related ikaite/glendonite formation // Marine Geology. 2004. Vol. 204. Is. 1-2. P. 129–144. doi: 10.1016/S0025-322703) 00354-2 Hachikubo A., Krylov A., Sakagami H., Minami H., Nunokawa Yu., Shoji H., Matveeva T., Jin Y.K., Obzhirov A. Isotopic composition of gas hydrates in subsurface sediments from offshore Sakhalin Island, Sea of Okhotsk // Geo-Mar Letters. 2010. Vol. 30. P. 313-319. doi: 10.1007/s00367-009-0178-y Hydro-Carbon Hydrate Accumulations in the Okhotsk Sea (CHAOS-II Project). Report of R/V Akademik M.A.Lavrentyev Cruise 36, Vladivostok - St.Petersburg, 2006a, 127 pages. Hydro-Carbon Hydrate Accumulations in the Okhotsk Sea (CHAOS-III Project). Report of R/V Akademik M.A. Lavrentyev Cruise 39, Vladivostok-Donghae-Korsakov-Okhotsk Sea-Vladivostok-Donghae-Vladivostok, 2006b, 132 pages. Kodina L. A., Tokarev V. G., Vlasova L. N., Korobeinik G. S. Contribution of biogenic methane to ikaite formation in the Kara Sea: Evidence from the stable carbon isotope geochemistry. Siberian river run-off in the Kara Sea. Eds. R. Stein, K. Fahl, D. K. Fuetterer, E. M. Galimov. Proc. Marine Science. Vol. 6. Amsterdam: Elsevier. 2003. P. 349-374. doi: 10.1016/S1568-2692(03)80045-1 Krylov A., Logvina E., Hachikubo A., Minami H., Nunokawa Yu., Shoji H., Mazurenko L., Matveeva T., Obzhirov A., K-Y. Jin. Authigenic carbonates related to gas seepage structures in the Sea of Okhotsk (NE offshore Sakhalin): results from the CHAOS project. 6th International Conference on Gas Hydrates (ICGH 2008), 2008, CD-ROM. Krylov A.A., Khlystov O.M., Hachikubo A., Minami H., Zemskaya T.I., Logvina E.A., Lomakina A.V. and Semenov P.B. The reconstruction of the mechanisms of problematic authigenic carbonates formation in diagenetic and catagenetic environments associated with the generation/oxidation of hydrocarbons // Limnology and Freshwater Biology. 2020. Vol. 4 (SI:7VBC). P. 928–930. doi: 10.31951/2658-3518–2020-A-4-928 Matveeva T.V., Soloviev V., Wallmann K., Obzhirov A. et al. Geochemistry of gas hydrate accumulation offshore NE Sakhaline Island (the Sea of Okhotsk): results from the KOMEX-2002 cruise // Geo-Mar Letters. 2003. Vol. 23. P. 278-288. doi: 10.1007/s00367-003-0150-1 Mazurenko L.L., Matveeva T.V., Prasolov E.M., Shoji H. et al. Gas hydrate forming fluids on the NE Sakhalin slope, Sea of Okhotsk. From: Long D., Lovell M.A., Rees J.G., Rochelle C.A. (eds) Sediment-Hosted Gas Hydrates: New Insight on Natural and Synthetic Systems // The Gological Society, London, Spec. Publ. 2009. Vol. 319. P. 51-72. doi: 10.1144/SP319.5 Milkov A.V. Worldwide distribution and significance of secondary microbial methane formed during petroleum biodegradation in conventional reservoirs // Organic Geochemistry. 2011. Vol. 42. Is. 2. P. 184‒207. doi: 10.1016/j.orggeochem.2010.12.003 Purgstaller B., Dietzel M., Baldermann A., Mavromatis V. Control of temperature and aqueous Mg2+/Ca2+ ratio on the (trans-)formation of ikaite // Geochimica et Cosmochimica Acta. 2017. Vol. 217. P. 128-143. doi: 10.1016/j.gca.2017.08.016 Rogov M., Ershova V., Vereshchagin O., Vasileva K., Mikhailova K., Krylov А. Database of global glendonite and ikaite records throughout the Phanerozoic // Earth System Science Data. 2021. Vol. 13. Is. 2. P. 343–356, doi: 10.5194/essd-13-343-2021 Rogov M., Ershova V., Gaina C., Vereshchagin O., Vasileva K., Mikhailova K., Krylov A. Glendonites throughout the Phanerozoic // Earth-Science Reviews. 2023. Vol. 241, 104430. P. 1-32. doi: 10.1016/j.earscirev.2023.104430 Schultz B., Thibault N., Huggett J. The minerals ikaite and its pseudomorph glendonite: Historical perspective and legacies of Douglas Shearman and Alec K. Smith // Proceedings of the Geologists' Association. 2022. Vol. 133. Is. 2. P. 176-192. doi: 10.1016/j.pgeola.2022.02.003 Selleck B.W., Carr P.F., Jones B.G. A review and synthesis of glendonites (pseudomorphs after Ikaite) with new data: assessing applicability as recorders of ancient coldwater conditions // Journal of Sedimentary Research. 2007. Vol. 77. Is. 11. P. 980-991. doi: 10.2110/jsr.2007.087 Tollefsen E., Stockmann G., Skelton A., Morth C.-M. Chemical controls on ikaite formation // Mineralogical Magazine. 2018. Vol. 82. Is. 5. P. 1119–1129. doi: 10.1180/mgm.2018.110 Wallmann R., Aloisi G., Haeckel M., Tishchenko P., Pavlova G., Greinert J., Kutterolf S., Eisenhauer A. Silicate weathering in anoxic marine sediments // Geochimica et Cosmochimica Acta. 2008. Vol. 72. Is. 12. P. 3067-3090. doi: 10.1016/j.gca.2008.03.026
|
|
Cite this article:
Krylov A.A., Logvina E.A., Semenov P.B., Bochkarev A.V., Kil A.O., Shatrova E.V., Goremykin Yu.V., Krinitsky P.I., Novikhina E.S., Smirnov Yu.Yu., Chazov A.O., Zykov E.A., Urvantsev D.M. Unusual authigenous carbonates (Mg-calcite and ikaite) in the gas hydrate-bearing structure "VNIIOkeangeologiya" (Deryugin Basin, Sea of Okhotsk) // Relief and Quaternary deposits of the Arctic, Subarctic and North-West Russia. 2023. Issue 10. P. 405-414. doi: 10.24412/2687-1092-2023-10-405-414
|
